xiaojuan yu

Fundamental gas-phase reactions of actinide complexes elucidate their chemistry. Gas-phase studies provide uniquely detailed information on underlying chemical properties that influence bond dissociation and activation…

Since the original elaboration of the peculiar spectroscopic and magnetic properties of cerocene [Ce(COT)2, COT = cyclooctatetraene], complexes featuring CeIV–C chemical bonds have gathered increasing interest among the scientific community…

Organometallic cerium(IV) complexes are challenging to isolate due to the oxidizing nature of the Ce(IV) cation, which readily reacts with reducing carbon-based ligands. In this study, we report two cerium(IV) alkyne complexes with terminal alkyne groups: 1-CEC≡CTMS and 1-CEC≡CPH…