Metal oxidation: A common mechanism from clusters to surfaces
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Gas-phase anionic clusters are model systems for surface oxidation and meteor radio afterglows: Temperature-dependent kinetics of Mn- + O2 (M = Al, Cr, Ni, Co, V)
The kinetics of Mn- + O2 (M = Al (n=1-17), Cr (n=1-15), Ni (n=1-14), Co (n=1-12), V (n=1-15) ) were measured from 300 to 600 K using a selected-ion flow tube apparatus. The Aln- anions, long believed to have stable values of n (e.g…
Metal oxidation: A common mechanism from clusters to surfaces
The Plasma Chemistry group at the Air Force Research Laboratory has long utilized temperature dependent kinetics to look at simple ion-molecule reactions with unprecedented mechanistic detail and recently have expanded to the kinetics of cluster systems…
Statistical modelling of temperature dependent kinetics: A simple approach often with complicated results
The Air Force Research Laboratory’s Plasma Chemistry Lab has long been tasked with studying the kinetics of charged species relevant to a host of plasma environments with significance to Air Force, and now Space Force as well, goals and interests…