Having access to a series of terminal and bridging nitrides supported with Tp_t_Bu,Me ligand (Tp_t_Bu,Me = hydrotris(3-_ter__t-_butyl-5-methylpyrazol-1-yl)borate) and in different oxidation states, namely [(Tp_t_Bu,Me)VV≡N(N3)], [(Tp_t_Bu,Me)VIV≡N(THF)], and [{(Tp_t_Bu,Me)VV(μ2−N)2}2VIV], we have e…
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Graduate Student, University of Pennsylvania
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University of Pennsylvania