Vanadyl is an attractive, earth-abundant first row transition metal oxidant, but could benefit from improved solubility in organic solvents and control of stereochemical outcome…
The Richman-Atkins synthesis transformed the accessibility of aliphatic azamacrocycle ligands 50 years ago and was almost immediately thereafter proposed to proceed via a Thorpe-Ingold (gem-disubstituent) effect…
Aliphatic hydroxamates are frequent chelating motifs in siderophores (molecules released by bacteria to acquire metals), but are rare in ligands designed for chelation of _f_-elements…
The Richman-Atkins synthesis transformed the accessibility of aliphatic azamacrocycle ligands 50 years ago and was almost immediately thereafter proposed to proceed via a Thorpe-Ingold (gem-disubstituent) effect…