Organic isocyanates are widely used in industrial applications such as preparation of polyurethanes, but their synthesis typically employs toxic and reactive phosgene as a C1 source. Our lab recently reported the preparation of adamantyl isocyanate by a different approach…
The Co=Si linkage in cobalt silylenes enables cooperative chemistry between the metal center and metalloid, expanding reactivity possibilities. This linkage is stabilized in a robust PSiP ligand framework with bulky _tert_-butyl substituents on the phosphine ligands…