The accessible aqueous tetravalent oxidation state of Ce4+ has been instrumental in its facile separation from other rare earth metals via redox processes…
Interest in redox flow batteries (RFBs) has increased because of their excellent performance in energy storage and a potential for addressing the solution to the issues of discontinuity and intermittency of renewable energy sources such as wind or solar…
Except for the dominant high-valent [An5+/6+O2]1+/2+ actinyl species or rare Np/Pu tetra(oxo) complexes exhibiting metal-ligand multiple bonding, stabilization of high-valent transuranic molecular compounds remains a significant challenge…
Control of the Ln3+/4+ redox potential through ligand design is a powerful tool for expanding the scarce family of Ln4+ molecular compounds. It is known that ligand configuration can play a crucial role in controlling many properties of complexes, including redox potentials…