Molten chloride salts (including MgCl₂, KCl, NaCl, and ZnCl₂) are being considered for heat transfer media for renewable (solar) and nuclear power generators, as a fuel for nuclear reactors, and as a thermal energy storage media. Impurities, such as oxygen, hydroxides, moisture, and sulfur, are known to negatively influence the corrosion of materials in contact with the salt (e.g., structural metals). Commercially available chloride salts come with a range of impurities. Before using the chloride salts at high temperature, it is desirable to remove the impurities to increase the performance of the salt and reduce corrosion. In this study, we tested the use of thionyl chloride vaporized into a stream of argon to react with oxygenated impurities in a mixture of MgCl₂-KCl-NaCl, removing them as HCl and SO₂. The reagent was bubbled through the salt when both above and below the melting point. The reaction was followed using thermocouple data from the salt and by Fourier Transform Infrared (FTIR) spectroscopy on the exhaust of the reactor. The reaction kinetics were followed by comparing the peaks from SO₂ product to SOCl₂ reagent in the FTIR spectra. The purity of the salt was assessed at the end of the purification process by X-ray diffraction and inductively coupled plasma analysis. While the process was effective at removing the oxygen content of the mixture, ternary compounds were formed in the process, including KNiCl₃ and KMgCl₃. The nickel in KNiCl₃ came from reaction between the salt and the nickel vessel. Thus, these experiments suggest that improvements to the process need to be made before using SOCl₂ vapors for the purification of chloride salts.

Dino Sulejmanovic

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