The chemistry of heterobimetallic compounds in which a redox-active metal is paired with a Lewis acidic, redox-inactive metal ion has become an area of intense interest in recent years…
Incorporation of Lewis acids into heterobimetallic complexes has emerged as an attractive strategy for modulating the thermochemical properties of redox-active compounds…
An appealing strategy for tuning the properties of redox-active metal complexes is incorporation of redox-inactive secondary metals into heteroditopic structures…
Placing two metal centers in close proximity offers an appealing strategy for engendering new properties that may not be accessible from only a single metal center…
The incorporation of redox-inactive Lewis acidic metals into redox-active compounds has sparked significant interest due to the potential for reliably modulating thermochemical properties and reactivity…
Reduction of high-valent uranium represents both a strategy for sequestration of this radioactive element from the environment as well as a key step in handling/recycling of nuclear fuels, but electron transfer to uranium via electrochemical methods has received less attention than it deserves…